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• W2041330256 abstract "Many hydrogen-bonded liquids, especially glass-forming cases, display a dielectric relaxation behavior that differs qualitatively from that of other simple liquids. The majority of models aimed at explaining this unusual dielectric behavior associate the prominent Debye process with structural relaxation, viscous flow, and the glass transition. We perform dielectric and calorimetric studies of glass-forming mixtures of 2-ethylhexylamine and 2-ethyl-1-hexanol across the entire composition range. The kinetic glass transition temperature derived from the large dielectric Debye peak decreases, whereas that of the much smaller and asymmetrically broadened peak increases upon addition of amine. Only the latter feature coincides with the calorimetric glass transition results, implying that molecular structure and dielectric polarization fluctuate on time scales that can differ by orders of magitude in many hydrogen-bonding liquids." @default.
• W2041330256 created "2016-06-24" @default.
• W2041330256 creator A5022333353 @default.
• W2041330256 creator A5066675483 @default.
• W2041330256 date "2005-05-12" @default.
• W2041330256 modified "2023-10-15" @default.
• W2041330256 title "Debye Type Dielectric Relaxation and the Glass Transition of Alcohols" @default.
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• W2041330256 doi "https://doi.org/10.1021/jp051965d" @default.
• W2041330256 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16852352" @default.
• W2041330256 hasPublicationYear "2005" @default.
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