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- W2041335019 abstract "The condensation of β-diketones, benzoylacetone (II), acetylacetone (III), or 6-phenyl-2,4-hexanedione (IV) with benzylidenaniline (I), in the presence of three moles of potassium amide in liquid ammonia, was found to give a dihydropyridone or an aminodiketone. Thus, the condensation of II with I afforded aminodiketone, 1-anilino-1,5-diphenyl-3,5-pentanedione (V), which cyclized to 2,3-dihydro-1,2,6-triphenyl-4-pyridone (IX) upon being treated with sulfuric acid. The condensation of III with I gave 2,3-dihydro-1,2-diphenyl-6-methyl-4-pyridone (X) without any treatment with sulfuric acid. IV and I gave 2,3-dihydro-1,2-diphenyl-6-phenethyl-4-pyridone (XI) as the main product, with 3-benzyl-2,3-dihydro-1,2-diphenyl-6-methyl-4-pyridone (XII) as a by-product." @default.
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- W2041335019 date "1969-05-01" @default.
- W2041335019 modified "2023-09-24" @default.
- W2041335019 title "A Novel Method for the Synthesis of 1-Phenyl-2,3-dihydro-4-pyridones" @default.
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- W2041335019 doi "https://doi.org/10.1246/bcsj.42.1357" @default.
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