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- W2041425685 abstract "The reaction of the double cubane [(Cl4-cat)MoFe3S4(PEt3)3]2 with CO in THF solution affords the neutral, heterometallic clusters (Cl4-cat)MoFe3S3(PEt3)2(CO)6, at 350 psi, and (Cl4-cat)Mo(O)Fe3S3(PEt3)3(CO)5, under ambient pressure. The corner-sulfide voided MoFe3S3 cuboidal cores of these clusters make them potentially useful synthetic precursors for a structural model of the Fe/Mo cofactor." @default.
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- W2041425685 title "New Fe/Mo/S Clusters with MoFe<sub>3</sub>S<sub>3</sub> Cuboidal Cores Similar to the One in the Fe/Mo Cofactor of Nitrogenase. Synthesis and Structural Characterization of the (C1<sub>4</sub>-cat)MoFe<sub>3</sub>S<sub>3</sub>(PEt<sub>3</sub>)<sub>2</sub>(CO)<sub>6</sub> and (C1<sub>4</sub>-cat)Mo(O)Fe<sub>3</sub>S<sub>3</sub>(PEt<sub>3</sub>)<sub>3</sub>(CO)<sub>5</sub> Clusters" @default.
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