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• W2041452766 abstract "Abstract C3‐vinyl and C13‐keto‐carbonyl groups of methyl pyropheophorbide‐ a , a chlorophyll‐ a derivative, were systematically modified to investigate the substituent effects along the y ‐axis of chlorin macrocycles. C13 1 deoxygenation resulted in blueshifts of the Q y absorption maxima and a large reduction of their redox potentials, whereas introduction of the dicyanomethylene group at the 13 1 ‐position caused the opposite effect on both optical and electrochemical properties. Among the nine chlorins examined, the Q y peak positions could be varied from 647 to 736 nm by the cooperative effects of the diagonal substituents' combinations." @default.
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• W2041452766 date "2010-08-03" @default.
• W2041452766 modified "2023-10-07" @default.
• W2041452766 title "Cooperative C3‐ and C13‐Substituent Effects on Synthetic Chlorophyll Derivatives" @default.
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• W2041452766 doi "https://doi.org/10.1002/ejoc.201000541" @default.
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