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- W2041461678 abstract "Taylor's seminal work on the nomenclature of organic chemistry remains a font for improving our understanding of chemical structure and taxonomy. This report first examines the impact of various aspects of topology in constructing an `efficient' taxonomy for molecular structure, with a view to including both organic and inorganic chemistry, and then extends this system into new directions not anticipatable when Taylor developed his organizational framework. Special emphasis is given to the dimensionality of the model used and the common practice of projecting a molecule into a planar surface and examining the simplified image so produced, with its faulty premise that such an image is isomorphic with the actual molecule. This is followed by examining the practice of modeling molecules using `simple' figures; in particular, the inherent mathematical problems associated with maintaining a bijection between a chemical molecule and a geometrical model. Such `mappings' are of special interest when the chemical molecule, and thus the associated mathematical model, does not have a `simple' geometry." @default.
- W2041461678 created "2016-06-24" @default.
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- W2041461678 date "1998-10-01" @default.
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- W2041461678 title "A modern topological perspective of ring compound taxonomy created by re-examining Taylor's nomenclature system" @default.
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- W2041461678 doi "https://doi.org/10.1016/s0166-1280(98)00178-x" @default.
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