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- W2041502047 abstract "Reactions between 1,2-dichlorohexafluorocyclopentene and Ru(CCH)(dppe)Cp∗ or Ru(CCCCLi)(dppe)Cp∗ have given Ru(CC-c-C5F6Cl-2)(dppe)Cp∗ 4 and Ru(CCCC-c-C5F6Cl-2)(dppe)Cp∗ 7, respectively. Ready hydrolysis of 4 to the ketone Ru{CC[c-C5F4Cl(O)]}(dppe)Cp∗ 5 occurs, which can be converted to Ru{CC(c-C5F4Cl[C(CN)2])}(dppe)Cp∗ 6 by treatment with CH2(CN)2/basic alumina. Spectroscopic, electrochemical and XRD structural studies for 4–7 are reported: for 6, these suggest that the cyanated fluorocarbon ligand is a very powerful electron-withdrawing group." @default.
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- W2041502047 date "2010-02-01" @default.
- W2041502047 modified "2023-10-17" @default.
- W2041502047 title "Some ruthenium complexes of fluorinated alkynylcyclopentenes" @default.
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- W2041502047 doi "https://doi.org/10.1016/j.jorganchem.2009.10.050" @default.
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