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- W2041503939 abstract "The technique of conversion-electron Mössbauer spectroscopy (CEMS) is based on the fact that during the decay of certain excited nuclear-spin states internal conversion processes, which involve the liberation of (conversion) electrons from ns orbitals, may occur. Because of the exceptionally high efficiency of the internal conversion of the 14.4 keV γ-ray in the decay of the I = ± 32 spin state of 57Fe, it is possible, by use of an appropriate proportional counter, to measure the total intensity of the conversion (and accompanying Auger) electrons as a function of the modulated incident γ-ray energy. This, therefore, permits of the Mössbauer study of surface regions of iron-bearing solids by monitoring the liberated electrons in a resonance-type experiment. The feasibility of the technique for the detection and identification of various new phases formed at the surfaces of partially oxidized iron foils has been established; and, in particular, the characterization of β-FeOOH, formed when iron is oxidized in wet-acid vapours, demonstrated." @default.
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- W2041503939 date "1974-10-01" @default.
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- W2041503939 title "Conversion-electron Mössbauer spectroscopy for the study of solid surfaces" @default.
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- W2041503939 doi "https://doi.org/10.1016/0039-6028(74)90191-5" @default.
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