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- W2041509985 abstract "The use of nitrogen- and carboxyl-containing monomers in conjunction with hydroxyalkyl acrylates and methacrylates enables hydrogels having equilibrium water contents in the range 30–90% to be obtained. Although such systems are described in the patent literature, the effect of structural variation on properties is not well recognized. In this paper, the effect of copolymer composition on equilibrium water content is discussed, together with the way in which water structure within the polymer varies. Although weakly interacting monomer pairs, such as hydroxyethyl methacrylate and vinylpyrrolidone, produce steady and predictable changes in polymer properties as a function of compositional variation, the same is not true of monomers that possess appreciable hydrogen-bonding capability. In such cases, typified by acrylamide-methacrylic acid and acrylamide-acrylic acid, hydrogen bonding between the constituent monomers produces the most marked structural effects at around equimolar feed ratios. The resultant interaction is reflected in equilibrium water content, mechanical properties and surface properties. The effect of composition on these properties (as measured by micropenetrometry and surface energy analyses) is discussed together with the results of more structure-specific biological probe experiments." @default.
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- W2041509985 date "1988-04-01" @default.
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- W2041509985 title "Synthetic hydrogels: 2. Copolymers of carboxyl-, lactam- and amide-containing monomers—structure/property relationships" @default.
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- W2041509985 doi "https://doi.org/10.1016/0032-3861(88)90086-9" @default.
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