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- W2041602743 abstract "Natural mixtures of sophorolipids produced by the yeast Candida bombicola have been analyzed by fast atom bombardment (FAB)-MS and collision-induced dissociation (CID)-MS. Some pure components have been analysed by two-dimensional NMR spectroscopy. The presence of acidic, lactonic, and O-acetylated forms and the position of double bonds in the fatty acid part of these glycolipids can be easily inferred from positive and negative ion FAB-mass spectra. Details about position of O-acetylation can be obtained from CID mass spectra of [M + H]+ and [M − H]− ions and from the NMR spectra. Differences in CID fragmentation between protonated and sodiated molecular ions are discussed in detail. Enzymatic hydrolysis of 6′,6″-di-O-acetyl sophorolipid lactone by cutinase from Fusarium solani results specifically in the removal of the 6′-O-acetyl group, whereas the 6″-O-acetyl and lactone group are resistant. This specificity is explained from a three-dimensional model of the sophorolipid generated on the basis of the short 1H, 1H distances as inferred from the NMR (ROESY) spectra." @default.
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- W2041602743 date "1995-09-01" @default.
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- W2041602743 title "Tandem Mass Spectrometry and Nuclear Magnetic Resonance Spectroscopy Studies of Candida bombicola Sophorolipids and Product Formed on Hydrolysis by Cutinase" @default.
- W2041602743 doi "https://doi.org/10.1006/abio.1995.1448" @default.
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