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• W2041632912 abstract "A new remediation technology for groundwater contaminated with chlorinated solvents is through contact with granular iron. To refine our understanding of the reaction mechanism, electrochemical and spectroscopic measurements were performed on iron electrodes in deaerated borate buffer containing an amount of a degradable (carbon tetrachloride) or non-degradable (dichloromethane) compound. The results of polarization measurements indicated that carbon tetrachloride acts as an oxidizer towards iron while dichloromethane is nonreactive. Magnetite and hydrated magnetite, identified by Raman spectroscopy, are the final products of the surface redox reactions. Based on electrochemical and spectral evidence, a new conceptual model for the reductive reactions is proposed." @default.
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• W2041632912 date "1998-08-01" @default.
• W2041632912 modified "2023-09-27" @default.
• W2041632912 title "Influence of chlorinated solvents on polarization and corrosion behaviour of iron in borate buffer" @default.
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• W2041632912 doi "https://doi.org/10.1016/s0010-938x(98)00042-0" @default.
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