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- W2041657963 abstract "A liquid−liquid phase-transfer catalysis (PTC) system investigated in this work consists of two immiscible liquid phases, n-butyl bromide (BuBr, with toluene as an organic solvent) and sodium phenolate (NaOPh, dissolved in water), each containing a reagent. To initiate the reaction between reagents a phase-transfer mechanism is required, which is accomplished through the use of a phase-transfer catalyst (PT-Cat). The PT-Cat transfers one reagent from one phase to the other, whereupon the other reagent can react with the catalyst−reagent transient. In our work two types of PT-Cat, i.e., benzyltributylammonium chloride (BTAC) and tetrabutylammonium bromide (TBAB), were used. The PTC reaction is performed in both an oscillatory baffled reactor (OBR) and a stirred tank reactor (STR). In this paper we report our experimental results of reaction rates in the two reactors for a range of operating conditions. Our preliminary results indicate that the OBR has the capability of enhancing reaction rates above those observed in the STR." @default.
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- W2041657963 date "2001-08-04" @default.
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- W2041657963 title "On the Investigation of a Phase-Transfer Catalysis Reaction in an Oscillatory Baffled Reactor" @default.
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- W2041657963 doi "https://doi.org/10.1021/ie001118r" @default.
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