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- W2041692005 abstract "The Group VI hexacarbonyls have been treated with potentially chelating ligands of the type CH2CHCH2CH2EMe2, where E = N, P, or As (nol, pol, and asol respectively). The amine forms solely chelate complexes with the general formula [M(CO)4(nol)] with each hexacarbonyl; however, the phosphine and arsine form not only chelate complexes with this general formula but also complexes with the general formulae [M(CO)4(CH2:CHCH2CH2EMe2)2] and [M(CO)5(CH2:CHCH2CH2EMe2)], in each of which the ligand is co-ordinated by way of the E atom only. The factors contributing to this behavioural difference between the ligands are discussed. For the complexes [M(CO)4(nol)] and [W(CO)4(pol)] variable-temperature i.r. studies are interpreted as indicating the presence of rotational isomers in solution. The mechanism whereby the isomers interconvert is discussed. The complexes [Mo(NO)2Cl2(asol)2] and [PdCl2(asol)] have been isolated from the reactions of asol with [Mo(NO)2Cl2] and [PdCl2(NCPh)2] respectively." @default.
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- W2041692005 date "1975-01-01" @default.
- W2041692005 modified "2023-09-26" @default.
- W2041692005 title "Complexes of Group VI hexacarbonyls with Group V ligands containing an olefinic side-chain" @default.
- W2041692005 doi "https://doi.org/10.1039/dt9750000468" @default.
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