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- W2041702010 abstract "We have computed cross sections and rate coefficients for rovibrational transitions in ortho- and para-H2, induced by ground state (v = 0, J = 1) ortho-H2. These results complement our previous calculations relating to excitation by para-H2 (v = 0, J = 0). The cross sections are found to be insensitive to the rotational state of the perturber. Discrepancies with measurements of the rate coefficient for v = 10 vibrational relaxation at low temperatures persist. The value of this rate coefficient at low temperatures is shown to be determined by a combination of the Wigner threshold law and the presence of a quantal interference minimum. Further experimental and theoretical work on the H2-H2 system is called for in order to resolve the remaining discrepancies." @default.
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- W2041702010 date "1999-07-20" @default.
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- W2041702010 title "Rovibrational relaxation in collisions between H<sub>2</sub>molecules: II. Influence of the rotational state of the perturber" @default.
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- W2041702010 doi "https://doi.org/10.1088/0953-4075/32/14/310" @default.
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