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- W2041733694 abstract "Polymerization of butene-1 was carried out with MgCl2TiCl4-Et3Alethylbenzoate (EB) or 2,2,6,6-tetramethylpiperidine (TMP) catalyst systems and the poly(butene-1) obtained was fractionated into n-decane (C10)-soluble and -insoluble portions. By 13C nuclear magnetic resonance analysis, the frequency of the mmmm pentad of each fraction was determined to be 30–34% for the C10-soluble and 78% for the C10-insoluble fractions. EB or TMP enhanced the stereospecificity by selective poisoning for the formation of C10-soluble polymer and increased the molecular weight of each fraction by a maximum 2–3 times without changing the polydispersity. EB was found to be superior to TMP as a stereospecificity improver." @default.
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- W2041733694 date "1987-06-01" @default.
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- W2041733694 title "Polymerization of butene-1 with highly active MgCl2- supported TiCl4 catalyst system" @default.
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- W2041733694 doi "https://doi.org/10.1016/0032-3861(87)90269-2" @default.
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