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• W2041759905 abstract "Scanning tunnelling microscopy has been used to study the interaction of dimethyl disulphide, (CH3S)2, with Cu(111) at room temperature, which is known to produce adsorbed methanethiolate, CH3S-, by SS bond scission at the surface. The results provide clear evidence for the formation of a pseudo-square surface reconstruction induced by the adsorbate; this reconstruction can be reconciled with the results of previous structural studies of this surface by the techniques of X-ray standing wave and surface extended X-ray absorption fine structure. Two further ordered adsorption phases are observed. One of these, a hexagonal honeycomb phase, is proposed to involve bridge and hollow site adsorption on an unreconstructed Cu surface and is metastable; it is identified as a methanethiolate species previously only studied at low temperature by photoelectron spectroscopy and X-ray standing waves. A third phase of hexagonal symmetry appears to be an alternative endpoint to the pseudo-square phase, but may be due to higher adsorbate coverages; the nature of the structure of the underlying copper surface in this case is unclear." @default.
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• W2041759905 date "2000-06-01" @default.
• W2041759905 modified "2023-09-27" @default.
• W2041759905 title "Scanning tunnelling microscopy study of the interaction of dimethyl disulphide with Cu(111)" @default.
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• W2041759905 doi "https://doi.org/10.1016/s0039-6028(00)00390-3" @default.
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