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- W2041796795 abstract "Abstract The standard enthalpies of formation for some rare earth stannides in the binary systems RESn (RE Sc, Y, Pr, Nd, Gd, Ho) have been determined by direct synthesis calorimetry at 1473 ± 2 K. The following values of ΔH f o kJ (mole of atoms) −1 are reported: Sc 5 Sn 3 = −70.2 ± 1.8; Y 5 Sn 3 = −72.8 ± 2.9; Pr 5 Sn 3 = −75.3 ± 1.4; Nd 5 Sn 3 = −74.1 ± 1.7; Gd 5 Sn 3 = −78.2 ± 2.8; Ho 5 Sn 3 = −73.5 ± 2.3. The results are compared with reported calorimetric data for the corresponding compounds of some other rare earth elements, with predicted values from the semi-empirical model of Miedema and coworkers, and with the predictions of Colinet et al. Possible correlations among the lanthanide compounds of the systematic changes in the enthalpies of formation, in the relative molar volume ratios and in the reduced temperatures as suggested by Gschneidner are also examined." @default.
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- W2041796795 date "1996-05-01" @default.
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- W2041796795 title "Standard enthalpies of formation of some rare earth stannides by high temperature direct synthesis calorimetry" @default.
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- W2041796795 doi "https://doi.org/10.1016/0925-8388(95)02190-6" @default.
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