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- W2041827782 abstract "The microwave spectrum of OCS trimer, measured between 6 GHz and 18 GHz using Fourier-transform microwave spectroscopy, is consistent with a very asymmetric rotor, k = 0·18. A- and c-type transitions are observed with many lines showing a fine doubling of less than 20 kHz. A fit of average line positions to Watson A reduction (IR) rotational parameters gives; A = 847·97958(2), B = 736·17579(2), C = 574·32591(1) MHz, Δ J = 0·45440(9), Δ JK = 0·1572(5), Δ K = 0·3010(5), δ J = 0·06797(4), δ K = 0·0339(3)kHz. From a sum of electrostatic and Lennard-Jones pair interaction potentials, the model trimer equilibrium structures are chiral, suggesting the observed splitting is the result of tunnelling interconversion between enantiomers. A scheme employing the recursion relation for associated Legendre polynomials is used to extend the distributed multipole method for the electrostatic interaction between linear molecules to include multipole moments up to the highest order available from ab initio calculations." @default.
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- W2041827782 date "1996-07-01" @default.
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- W2041827782 title "Internal motion effects in the microwave spectrum of OCS trimer" @default.
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- W2041827782 doi "https://doi.org/10.1080/00268979650025975" @default.
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