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- W2041842819 abstract "The oxidation of the 1,2,3,4-thiatriazole-5-thiolate ion, CS(2)N(-)(3), by permanganate ions in alkaline medium has been investigated over a wide range of oxidant concentrations. With a moderate excess of permanganate ion a 17-electron reaction takes place, yielding sulphate, nitrogen and carbon dioxide. With a high permanganate concentration the pseudohalide undergoes a 26-electron reaction yielding sulphate, carbon dioxide and nitrite as final products. These two different stoichiometries arise from the existence of competitive mechanisms and the ratio C(MnO(-)(4))/C(CS(2)N(-)(3)) will determine the course of the reaction." @default.
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- W2041842819 date "1981-11-01" @default.
- W2041842819 modified "2023-09-26" @default.
- W2041842819 title "Evidence of competitive mechanisms during oxidation of CS2N−3 by permanganate ion in alkaline solution" @default.
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- W2041842819 doi "https://doi.org/10.1016/0039-9140(81)80034-3" @default.
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