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- W2041871027 abstract "The nitrogen NMR shielding of tert-butyl isocyanide (1) is shown to be a sensitive probe of solvent polarizability–polarity, since the shielding is demonstrated to be unresponsive to hydrogen bonding effects between 1 and the solvent. The direction of solvent effects observed is explained in terms of the solvaton model, used within the INDO/S–SOS framework. A comparison is made with solvent-induced nitrogen shielding variations of the corresponding isomeric covalent cyanides." @default.
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- W2041871027 date "1992-02-01" @default.
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- W2041871027 title "Solvent-induced variations in nitrogen NMR shieldings oftert-butyl isocyanide as a probe for solvent polarizability-polarity" @default.
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- W2041871027 doi "https://doi.org/10.1002/mrc.1260300214" @default.
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