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- W2041894553 abstract "Methyl 3,4-di-(2'-hydroxyethoxy)benzylidenecyanoacetate (3) was prepared by hydrolysis of methyl 3,4-di-(2'-vinyloxyethoxy)benzylidenecyanoacetate (2). Diol 3 was condensed with 2,4-toluenediisocyanate, 3,3'-dimethoxy-4,4'-biphenylenediisocyanate, and 1,6-hexamethylenediisocyanate to yield polyurethanes 4, 5 and 6 containing the non-linear optical (NLO) chromophore 3,4-dioxybenzylidenecyanoacetate. The resulting polyurethanes 4-6 were soluble in common organic solvents such as acetone and DMF. T g values of the polymers obtained from DSC thermograms were in the range 80-102 °C. Polymers 4-6 showed thermal stability up to 300 °C in TGA thermograms, and electrooptic coefficients (r 33 ) of the poled polymer films were in the range 10-12 pm V -1 at 633 nm, which are acceptable for NLO device applications." @default.
- W2041894553 created "2016-06-24" @default.
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- W2041894553 date "2002-01-01" @default.
- W2041894553 modified "2023-09-27" @default.
- W2041894553 title "Synthesis of novel polyurethanes containing dioxybenzylidenecyanoacetate, as non-linear optical chromophores and their properties" @default.
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- W2041894553 doi "https://doi.org/10.1002/pi.828" @default.
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