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- W2041896945 abstract "Intercalation of halogens (Cl, Br, I) into tetragonal modification of YBa2Cu3O7−x is realized. The new halogen-containing compounds are the high-temperature superconductors. Mössbauer's spectroscopy shows that in general the halogens are localized in oxygen vacancies of the Cu(1) layer, and the intercalation is accompanied by the charge transfer from the Cu(2) layers on to the halogens. So, the high-temperature superconductivity (HTSC) is determined by the certain concentration of holes in the Cu(2) layers which arises as a result of intercalation of acceptors of different types into the Cu(1) layers. The possible versions of explanation of appearance of HTSC in the given compounds are considered." @default.
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- W2041896945 date "1989-10-01" @default.
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- W2041896945 title "Intercalation of halogens into tetragonal YBa2Cu3O7−x" @default.
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- W2041896945 doi "https://doi.org/10.1016/0038-1098(89)90889-2" @default.
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