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• W2041912719 abstract "Abstract A new lanthanum complex formulated as {(bpyH2)[La(btc)(H2O)4(NO3)]·2H2O}n (1) (btcH4=benzene-1,2,4,5-tetracarboxylic acid; bpy=4,4′-bipyridine) was hydrothermally synthesized. The complex was characterized by FT-IR spectroscopy, elemental analysis and X-ray diffraction. X-ray crystal structural analysis revealed that the compound belonged to the monoclinic space group C2/c with cell parameters a= 1.42806(7) nm, b=1.10258(5) nm, c=1.60333(8) nm and β=101.9400(10)°. The complex was polymeric with LaIII atoms linked by four O atoms from two carboxylate groups of one benzene-1,2,4,5-tetracarboxylate. The LaIII atom was ten coordinated in a distorted tetracapped trigonal prism. In the crystal structure, a wide range of noncovalent interactions consisting of hydrogen bonding (of the types of O—H…O, N—H…O and C—H…O) and ion pairing interactions connected the various components into a supramolecular structure." @default.
• W2041912719 created "2016-06-24" @default.
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• W2041912719 date "2009-06-01" @default.
• W2041912719 modified "2023-10-16" @default.
• W2041912719 title "Hydrothermal synthesis and structural studies of a new coordination polymer of lanthanum(III) with benzene-1,2,4,5-tetracarboxylic acid and 4,4′-bipyridine" @default.
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• W2041912719 doi "https://doi.org/10.1016/s1002-0721(08)60250-1" @default.
• W2041912719 hasPublicationYear "2009" @default.
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