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- W2041939043 abstract "Abstract The cross-linking reaction of poly(styrene- co -maleic anhydride) (SMA) with ethylene glycol (EG) was monitored using size exclusion chromatography. On-line viscosity and static light scattering detection provided [ η ] and R g for structural analysis of the cross-linking intermediates. With increasing reaction time a decrease of the expansion exponent α of the Kuhn–Mark–Houwink–Sakurada relationship was observed. A change from coiled structures to spherical molecules during the cross-linking reaction was confirmed by analyzing the fractal dimensions of the molecules after different reaction times. The calculation of the branching parameters g and g ′ revealed the formation of contracted branched molecules. The connection of SMA chains by EG leads to a contraction of the polymers with increasing molecular weight." @default.
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- W2041939043 date "2010-05-01" @default.
- W2041939043 modified "2023-09-23" @default.
- W2041939043 title "Random cross-linked poly(styrene-co-maleic anhydride): Characterization of cross-linking intermediates by size exclusion chromatography" @default.
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- W2041939043 doi "https://doi.org/10.1016/j.eurpolymj.2010.01.024" @default.
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