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- W2041942015 abstract "Abstract The ligand, 4-methyl imidazole(L), forms a wide variety of new coordination complexes with cobalt(II) and nickel(II) ions. The complexes obtained by the direct reaction of metal salts, containing anions ranging from small and strongly coordinating to those usually believed to be noncoordinating, and the ligand, are of the type [ML6]X2, [ML6]X(ClO4), [NiL6][HgCl4], [NiL4(NCS)2], [NiL4(NCS)(ClO4)], [NiL2(NCS)2] having 6-coordinated octahedral or distorted octahedral structures, and [NiLCl2] and [Me4N][NiLCl3] with a tetrahedral structure. The [ML6](NCS)2 complexes contain ionic thiocyanate group, the [NiL4(NCS)2] and [NiL4(NCS)(ClO4)] contain N-bonded iso-thiocyanate groups, whereas the [NiL2(NCS)2] has bridging thiocyanate groups. Except for nickel(II) thiocyanate, attempts to prepare bis- or tetrakis-complexes by direct reaction resulted only in an oily mass and no stable compound could be prepared. The stoichiometry and stereochemistry of the complexes have been deduced on the basis of analytical data, electronic and IR spectra, molar conductance and room temperature magnetic susceptibility measurements. Thermal decomposition of the parent hexakis complexes [ML6]+2 at 130°C gave tetrahedral Co(II) complexes, e.g. [CoL4]X2 (X = ClO4, BF4) and [CoL2X2] (X = Cl, Br, I, NCS) and tetragonally distorted trans-octahedral complexes, [NiL4X2] (X = Cl, Br, I)." @default.
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- W2041942015 date "1977-01-01" @default.
- W2041942015 modified "2023-09-27" @default.
- W2041942015 title "Ligating ability of 4-methyl imidazole: Complexes with cobalt(II) and nickel(II)" @default.
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- W2041942015 doi "https://doi.org/10.1016/0022-1902(77)80388-6" @default.
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