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- W2041944355 abstract "Emission spectra of the CN(B2Σ+–X2Σ+) and CH(A2Δ–X2Π) transitions were observed in the dissociative excitation reaction of CH3CN with the microwave-discharge flow of Ar. The H2O molecules contained in the starting materials and adsorbed on the wall of the apparatus were removed by using P2O5 as a desiccant. The pressure of Ar, PAr, was in the range of 0.1–1.0 Torr. The ratio of the concentrations of the CH(A2Δ) and CN(B2Σ+) states, NCH(A)/NCN(B), in the desiccated system was found to be smaller than that in the system without desiccation. The [N]/([N]+[C]) ratio of the a-CNx:H films formed in the desiccated system was predicted to be ≈0.18, being nearly independent of PAr." @default.
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- W2041944355 date "2003-06-15" @default.
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- W2041944355 title "Dissociative Excitation Reaction of CH<sub>3</sub>CN with the Discharge Flow of Ar: Prediction of the [N]/([N]+[C]) Ratio of Hydrogenated Amorphous Carbon Nitride Films in the Desiccated System" @default.
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- W2041944355 doi "https://doi.org/10.1143/jjap.42.3684" @default.
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