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• W2041949678 abstract "The addition of 2,2'-bipyridine to [U(Tp(Me2))(2)I] (1) results in the displacement of the iodide and the formation of the cationic uranium(III) complex [U(Tp(Me2))(2)(bipy)]I (2). This compound was isolated as a dark-green solid in good yield and characterized by IR and NMR spectroscopies, and its molecular structure was determined by single-crystal X-ray diffraction. Studies of its magnetic properties revealed a frequency dependence of magnetization with a blocking temperature of 4.5 K and, at lower temperatures, a slow relaxation of magnetization with an energy barrier of 18.2 cm(-1), characteristic of single-molecule-magnet behavior." @default.
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• W2041949678 date "2011-09-14" @default.
• W2041949678 modified "2023-10-18" @default.
• W2041949678 title "[U(Tp^Me2)₂(bipy)]⁺: A Cationic Uranium(III) Complex with Single-Molecule-Magnet Behavior" @default.
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• W2041949678 doi "https://doi.org/10.1021/ic200705p" @default.
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