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- W2041954469 abstract "Rates of hydrolysis at 40° of the benzylidene residue in methyl 4,6-O-benzylidene-d-hexosides by 96% aqueous ethanol which was 0·03 M in hydrochloric acid, have been measured. The hexosides were of the α- and β-gluco-, α- and β-galacto-, α-manno, α-altro- and α-ido-configurations. Similar hydrolyses were carried out with the 4,6-O-benzylidene derivatives of methyl 3-deoxy-α-d-glucoside and methyl 2,3-di-O-methyl-α-d-glucoside. It was shown that under the conditions specified no cleavage of the glycosidic bond occurred with any of the samples. As the rate differences are small it is concluded that the geometry of the transition state corresponds closely to that of the initial state. Possible reasons for some of the rate differences observed are discussed in terms of steric and electronic features of the compounds." @default.
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- W2041954469 date "1961-01-01" @default.
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- W2041954469 title "The kinetics of the acid-catalysed hydrolysis of some methyl 4,6-O-benzylidene-hexosides" @default.
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- W2041954469 doi "https://doi.org/10.1016/0040-4020(61)80060-4" @default.
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