Matches in SemOpenAlex for { <https://semopenalex.org/work/W2042014494> ?p ?o ?g. }
Showing items 1 to 86 of
86
with 100 items per page.
- W2042014494 endingPage "2524" @default.
- W2042014494 startingPage "2518" @default.
- W2042014494 abstract "Gas phase rovibrational analysis of ν1, ν2, and ν3 vibrationally predissociating fundamentals arising from D–F, D–C, and C≡N stretching vibrations of DCN–DF are reported. The rotational substructure in these fundamentals and a total of five associated hot bands have been assigned, thus providing precisely determined band origin frequencies, distortion, and rotational constants. The following molecular parameters were determined for the three fundamentals (in cm−1): ν0(ν1)=2730.8909(2), ν0(ν2)=2638.1309(1), ν0(ν3)=1943.0046(3), B0=0.111 807(1), D0J =0.1946(4)×10−6, α1=0.001 449(2), α2=−0.003 00(1), α3=−0.000 399(1). The l-type doubling constants q″7 =0.378(3)×10−3 and q7 =0.380(3)×10−3 cm−1 were determined from the observed splitting in ν2+ν17−ν17. Anharmonic cross terms X027 =−0.600(3) and X037 =−0.61(3) cm−1 were also evaluated. Lifetimes of the ν1, ν2, and ν3 excited states were demonstrated to be 5.7(6)×10−10, 5.2(5)×10−9, and 3.0(5)×10−9 s, respectively." @default.
- W2042014494 created "2016-06-24" @default.
- W2042014494 creator A5007186160 @default.
- W2042014494 creator A5024966005 @default.
- W2042014494 creator A5031800254 @default.
- W2042014494 date "1987-03-01" @default.
- W2042014494 modified "2023-09-25" @default.
- W2042014494 title "Predissociating fundamental vibrations of DCN‐‐‐DF" @default.
- W2042014494 cites W1966816179 @default.
- W2042014494 cites W1968162931 @default.
- W2042014494 cites W1976074776 @default.
- W2042014494 cites W1983903306 @default.
- W2042014494 cites W1987065260 @default.
- W2042014494 cites W2018015066 @default.
- W2042014494 cites W2043522800 @default.
- W2042014494 cites W2053938698 @default.
- W2042014494 cites W2070580442 @default.
- W2042014494 cites W2078665311 @default.
- W2042014494 cites W2084275241 @default.
- W2042014494 cites W2087884307 @default.
- W2042014494 cites W2089984113 @default.
- W2042014494 cites W2149209075 @default.
- W2042014494 cites W2153380507 @default.
- W2042014494 doi "https://doi.org/10.1063/1.452104" @default.
- W2042014494 hasPublicationYear "1987" @default.
- W2042014494 type Work @default.
- W2042014494 sameAs 2042014494 @default.
- W2042014494 citedByCount "17" @default.
- W2042014494 countsByYear W20420144942018 @default.
- W2042014494 crossrefType "journal-article" @default.
- W2042014494 hasAuthorship W2042014494A5007186160 @default.
- W2042014494 hasAuthorship W2042014494A5024966005 @default.
- W2042014494 hasAuthorship W2042014494A5031800254 @default.
- W2042014494 hasConcept C111806078 @default.
- W2042014494 hasConcept C113196181 @default.
- W2042014494 hasConcept C121332964 @default.
- W2042014494 hasConcept C127413603 @default.
- W2042014494 hasConcept C147724859 @default.
- W2042014494 hasConcept C167812310 @default.
- W2042014494 hasConcept C178790620 @default.
- W2042014494 hasConcept C181500209 @default.
- W2042014494 hasConcept C184779094 @default.
- W2042014494 hasConcept C185592680 @default.
- W2042014494 hasConcept C198394728 @default.
- W2042014494 hasConcept C32909587 @default.
- W2042014494 hasConcept C43617362 @default.
- W2042014494 hasConcept C62520636 @default.
- W2042014494 hasConcept C66938386 @default.
- W2042014494 hasConcept C99679407 @default.
- W2042014494 hasConceptScore W2042014494C111806078 @default.
- W2042014494 hasConceptScore W2042014494C113196181 @default.
- W2042014494 hasConceptScore W2042014494C121332964 @default.
- W2042014494 hasConceptScore W2042014494C127413603 @default.
- W2042014494 hasConceptScore W2042014494C147724859 @default.
- W2042014494 hasConceptScore W2042014494C167812310 @default.
- W2042014494 hasConceptScore W2042014494C178790620 @default.
- W2042014494 hasConceptScore W2042014494C181500209 @default.
- W2042014494 hasConceptScore W2042014494C184779094 @default.
- W2042014494 hasConceptScore W2042014494C185592680 @default.
- W2042014494 hasConceptScore W2042014494C198394728 @default.
- W2042014494 hasConceptScore W2042014494C32909587 @default.
- W2042014494 hasConceptScore W2042014494C43617362 @default.
- W2042014494 hasConceptScore W2042014494C62520636 @default.
- W2042014494 hasConceptScore W2042014494C66938386 @default.
- W2042014494 hasConceptScore W2042014494C99679407 @default.
- W2042014494 hasIssue "5" @default.
- W2042014494 hasLocation W20420144941 @default.
- W2042014494 hasOpenAccess W2042014494 @default.
- W2042014494 hasPrimaryLocation W20420144941 @default.
- W2042014494 hasRelatedWork W1623583740 @default.
- W2042014494 hasRelatedWork W1977290489 @default.
- W2042014494 hasRelatedWork W2042014494 @default.
- W2042014494 hasRelatedWork W2042595795 @default.
- W2042014494 hasRelatedWork W2060374637 @default.
- W2042014494 hasRelatedWork W2090040036 @default.
- W2042014494 hasRelatedWork W2131880765 @default.
- W2042014494 hasRelatedWork W2136225388 @default.
- W2042014494 hasRelatedWork W2153380507 @default.
- W2042014494 hasRelatedWork W4293101436 @default.
- W2042014494 hasVolume "86" @default.
- W2042014494 isParatext "false" @default.
- W2042014494 isRetracted "false" @default.
- W2042014494 magId "2042014494" @default.
- W2042014494 workType "article" @default.