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- W2042023478 abstract "The polarised electronic spectra of MnO42– doped into crystals of Rb2SO4, Cs2SO4, and K2CrO4 have been recorded at 4·2 K in the range 10 000–40 000 cm–1. The different polarisation behaviour of the low-symmetry components of the 2T2 terms derived from the ligand-field and charge-transfer configurations is ascribed to differences in the magnitude of the spin-orbit interaction in the two types of configuration. From an analysis of the phonon sidebands in the ligand-field spectrum, comments are made about the phonon spectra of the host lattices. Shifts in the ligand-field and charge-transfer origins on changing the host lattice are also discussed." @default.
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- W2042023478 date "1973-01-01" @default.
- W2042023478 modified "2023-10-16" @default.
- W2042023478 title "Crystal lattice effects on the electronic spectrum of the manganate ion" @default.
- W2042023478 doi "https://doi.org/10.1039/dt9730002595" @default.
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