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• W2042048832 abstract "Based on the pillar[5]arene/imidazolium recognition motif, a [2]rotaxane was effectively prepared. Solvent/temperature triggered molecular motions of the pillar[5]arene ring on the imidazolium axle were successfully realized. By comparison of proton NMR spectra of the [2]rotaxane in different solvents, we found that if we increased the solvent polarity, the pillar[5]arene ring gradually moved away from the imidazolium part. In DMSO, we also could adjust the binding site of the pillar[5]arene ring by changing the temperature. Furthermore, in DMSO, the [2]rotaxane self-assembled to form a supramolecular gel, which showed multiple stimuli-responsiveness." @default.
• W2042048832 created "2016-06-24" @default.
• W2042048832 creator A5018080504 @default.
• W2042048832 creator A5045716658 @default.
• W2042048832 creator A5074785478 @default.
• W2042048832 date "2014-01-01" @default.
• W2042048832 modified "2023-10-16" @default.
• W2042048832 title "A pillar[5]arene/imidazolium [2]rotaxane: solvent- and thermo-driven molecular motions and supramolecular gel formation" @default.
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• W2042048832 doi "https://doi.org/10.1039/c3sc52481g" @default.
• W2042048832 hasPublicationYear "2014" @default.
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