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- W2042051208 abstract "[reaction: see text] The enantio- and diastereomerically pure Pd complex of the tropos biphenylphosphine (BIPHEP) ligand is obtained through complexation of the enantiopure (R)-diaminobinaphthyl (DABN) with either enantiomer of the BIPHEP-Pd catalyst, followed by tropo-inversion of the less favorable (S)-BIPHEP-Pd/(R)-DABN diastereomer to the more favorable (R)-BIPHEP-Pd/(R)-DABN diastereomer. The enantiopure BIPHEP-Pd catalyst with DABN affords higher enantioselectivity and catalytic efficiency as an activated Lewis acid catalyst than the enantiopure BIPHEP-Pd catalyst without DABN." @default.
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- W2042051208 date "2001-12-15" @default.
- W2042051208 modified "2023-10-16" @default.
- W2042051208 title "Asymmetric Activation of the Pd Catalyst Bearing the <i>Tropos </i>Biphenylphosphine (BIPHEP) Ligand with the Chiral Diaminobinaphthyl (DABN) Activator<sup>1</sup>" @default.
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- W2042051208 doi "https://doi.org/10.1021/ol0169675" @default.
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