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- W2042071177 abstract "The partition constants Ktominus of tris(acetylacetonato)chromium(III) between dodecane and water–organic solvent mixtures have been measured. The organic solvents used as co-solvents were acetonitrile, N,N-dimethylformamide, methanol, ethylene glycol, and dimethyl sulfoxide which are all miscible with water but not with dodecane. From the temperature dependence of Ktominus the thermodynamic parameters for the transfer of the complex from dodecane to the mixed solvents have been determined. The dependences of the partition constants on solvent composition of the aqueous phase have been interpreted in terms of changes in the internal pressure and the volume upon mixing of water with the organic co-solvents. The standard transfer enthalpies have been correlated with the excess enthalpies of the mixed solvents." @default.
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- W2042071177 date "1980-01-01" @default.
- W2042071177 modified "2023-09-26" @default.
- W2042071177 title "Partition of Tris(acetylacetonato)chromium(III) and Its Temperature Dependence in the Systems of Dodecane/(Water–Organic Solvent Mixture)" @default.
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- W2042071177 doi "https://doi.org/10.1246/bcsj.53.133" @default.
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