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- W2042072304 abstract "Addition-cyclization of vinyldiazomethane with various olefins has been investigated. The products consisted of vinylpyrazolines, cyclopropanes and dienes. From methyl acrylate, a small amount of cyclopentenylcarboxylate was also obtained, the formation of which was interpreted as being due to the 1,5-dipolar structure of vinyldiazomethane. Generalized mechanisms concerned with addition-cyclization of vinyldiazomethane and with decomposition of intermediates have been presented, the latter involves a competition of carbanion- and hydride-attack on the carbonium ion moiety." @default.
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- W2042072304 date "1967-01-01" @default.
- W2042072304 modified "2023-10-09" @default.
- W2042072304 title "Addition-cyclization of vinyldiazomethane with unsaturated compounds" @default.
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- W2042072304 doi "https://doi.org/10.1016/0040-4020(67)85126-3" @default.
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