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- W2042141896 abstract "The large undercoolings required for glass formation have been achieved by the slow cooling (10-20°C/min) of liquid Te-Cu alloys in the form of a fine droplet emulsion. Within the region of glass formation, between 19 and 39 at.% Cu, DTA measurements indicate that the glass (Tg) and crystallization (Tc) temperatures during heating exhibit a broad maximum at the eutectic. During slow cooling of Te-rich alloy droplets, the maximum undercooling for nucleation increases from 213°C for pure Te to 264°C for Te-12.5 at.% Cu. An enhanced depression of the nucleation (Tn) temperature compared with the change of the liquidus develops in Te-rich alloys upon approaching the glass forming composition range and can be a useful feature in assessing the glass forming tendency. Thermal cycling experiments indicate that even at an undercooling of 181°C crystallization in an eutectic Te-29 at.% Cu alloy is limited by an inadequate nucleation rate in clean droplet samples. For a eutectic alloy, at undercoolings in excess of 200°C crystal nucleation does develop in the droplet samples, but complete crystallization is hindered by a rapidly rising liquid viscosity with increased undercooling." @default.
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- W2042141896 date "1975-09-01" @default.
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- W2042141896 title "The effect of the properties of alloying components on the vitrification ability as exemplified by some tellurium alloys" @default.
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- W2042141896 doi "https://doi.org/10.1016/0036-9748(75)90537-2" @default.
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