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- W2042170102 abstract "This paper reports results of nuclear induction experiments on two isomorphic single crystals of Tutton's salts, ${mathrm{Rb}}_{2}$Mg${(mathrm{S}{mathrm{O}}_{4})}_{2}$ifmmodecdotelsetextperiodcenteredfi{}6${mathrm{H}}_{2}$O and ${mathrm{Cs}}_{2}$Mg${(mathrm{S}{mathrm{O}}_{4})}_{2}$ifmmodecdotelsetextperiodcenteredfi{}6${mathrm{H}}_{2}$O, belonging to crystal class $frac{P{2}_{1}}{a}$. The splittings, due to nuclear electric quadrupole interactions, of the nuclear magnetic resonance spectra of ${mathrm{Rb}}^{87}$ and ${mathrm{Cs}}^{133}$ observed in these experiments are analyzed by using perturbation theory. Analysis of the data yields a quadrupole coupling constant for ${mathrm{Rb}}^{87}$ of $|frac{mathrm{eQq}}{h}|=3141ifmmodepmelsetextpmfi{}35$ kc/sec, and the asymmetry of the field gradient at the nuclear site is $ensuremath{eta}=frac{({ensuremath{varphi}}_{mathrm{xx}}ensuremath{-}{ensuremath{varphi}}_{mathrm{yy}})}{{ensuremath{varphi}}_{mathrm{zz}}}=0.47ifmmodepmelsetextpmfi{}0.01$. The principal axis of the field gradient is directed toward the nearest sulfate ion but no correlation of asymmetry and near neighbor locations is observed.Comparison of the magnitudes of the field gradient at the nuclear sites of Rb and Cs were obtained by comparing the observed line patterns for the symmetry axis rotations, using the known moments of Cs and Rb. The complexity of the Cs spectra precluded a more complete comparison of the electric field symmetry." @default.
- W2042170102 created "2016-06-24" @default.
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- W2042170102 date "1956-11-15" @default.
- W2042170102 modified "2023-09-26" @default.
- W2042170102 title "Nuclear Quadrupole Interactions in Two Tutton's Salts" @default.
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- W2042170102 doi "https://doi.org/10.1103/physrev.104.932" @default.
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