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- W2042186786 abstract "Halogenated 1,3,5-triazapentadienyl ligands [N{(C3F7)C(C6F5)N}2]−, [N{(CF3)C(C6F5)N}2]− and [N{(C3F7)C(2,6-Cl2C6H3)N}2]−, alone or in combination with other N-donors like CH3CN, CH3(CH2)2CN, and N(C2H5)3, have been used in the stabilization of thermally stable, two-, three- or four-coordinate silver(I) adducts. X-Ray crystallographic analyses of {[N{(C3F7)C(C6F5)N}2]Ag}n, {[N{(C3F7)C(C6F5)N}2]Ag(NCCH3)}n, {[N{(C3F7)C(2,6-Cl2C6H3)N}2]Ag(NCCH3)}n, {[N{(CF3)C(C6F5)N}2]Ag(NCCH3)2}n and {[N{(C3F7)C(C6F5)N}2]Ag(NCC3H7)}n revealed the presence of bridging 1,3,5-triazapentadienyl ligands bonded to silver through terminal nitrogen atoms. These adducts are polymeric in the solid state. [N{(C3F7)C(2,6-Cl2C6H3)N}2]AgN(C2H5)3 is monomeric and features a 1,3,5-triazapentadienyl ligand bonded to Ag(I) in a κ1-fashion via only one of the terminal nitrogen atoms. The solid state structure of [N{(C3F7)C(C6F5)N}2]H has also been reported and it forms polymeric chains via inter-molecular N–H⋯N hydrogen-bonding." @default.
- W2042186786 created "2016-06-24" @default.
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- W2042186786 date "2011-01-01" @default.
- W2042186786 modified "2023-09-27" @default.
- W2042186786 title "Synthesis and characterization of silver(i) adducts supported solely by 1,3,5-triazapentadienyl ligands or by triazapentadienyl and other N-donors" @default.
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- W2042186786 doi "https://doi.org/10.1039/c1dt10199d" @default.
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