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- W2042193344 abstract "The effect of surface termination on C $1s$ core-level bulk excitons found near the surface in single-crystal diamond is reported. By simultaneously recording bulk (total electron yield) and surface (partial electron yield) near-edge x-ray absorption fine-structure (NEXAFS) spectra with a range of single-crystal surface terminations, variable bulk exciton energy blueshifts and linewidth broadening were observed, most notably in the reconstructed single-crystal diamond. Investigation of polycrystalline diamond and ultrananocrystalline diamond films, using the same technique, allowed for a comparison between the reconstructed single-crystal diamond surface and nanodiamond bulk excitons. These findings suggest that surface-related effects can be misinterpreted as quantum confinement in some nanodiamond NEXAFS studies. Band bending is suggested as a possible contributor to these results." @default.
- W2042193344 created "2016-06-24" @default.
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- W2042193344 date "2010-09-15" @default.
- W2042193344 modified "2023-09-25" @default.
- W2042193344 title "Diamond C<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:mn>1</mml:mn><mml:mi>s</mml:mi></mml:mrow></mml:math>core-level excitons: Surface sensitivity" @default.
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- W2042193344 doi "https://doi.org/10.1103/physrevb.82.125427" @default.
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