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• W2042205217 startingPage "10399" @default.
• W2042205217 abstract "In contrast with previously reported examples of benzene chemisorbed on metal surfaces with parallel orientation, adsorption of a Pd(110) surface appears to produce a tilted ring. Polarized light angle-resolved ultraviolet photoelectron spectroscopy (ARUPS) experiments in the mirror planes of the surface show that the adsorbate spectra give the expected strong polarization effects in the [001] azimuth but not in the [1ifmmodebarelsetextasciimacronfi{}10] azimuth. The azimuthal orientation of the ring is determined, and a tilt of the molecule of the order of 10ifmmode^circelsetextdegreefi{}-20ifmmode^circelsetextdegreefi{} into the grooves of the surface, towards [001] is proposed, so that the overall symmetry is reduced to ${C}_{s}$. A sharp $c(4ifmmodetimeselsetexttimesfi{}2)$ lowenergy electron-diffraction (LEED) pattern is observed. The azimuthal orientation and the tilt determined from ARUPS are those required to minimize steric interactions in a model for the LEED pattern." @default.
• W2042205217 created "2016-06-24" @default.
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• W2042205217 date "1988-06-15" @default.
• W2042205217 modified "2023-09-26" @default.
• W2042205217 title "Benzene on Pd(110): The first example of nonparallel adsorption" @default.
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• W2042205217 doi "https://doi.org/10.1103/physrevb.37.10399" @default.
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