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- W2042218564 abstract "The ultraviolet absorption, linear dichroism, circular dichroism, and oriented circular dichroism of collagen are reported and the spectra are resolved into a self-consistent set of bands in accord with exciton theory. The parallel band at 200 nm has 40% of the π → π* intensity; the perpendicular band is placed at 189 nm yielding a splitting of 2700 cm−1. The circular dichroism is resolved into two Gaussians at λ∥ and λτ (rotational strengths +14 × 10−40 and −32 × 10−40 esu2. cm2) plus a large non-Gaussian (“helix”) band with ampplitude −25,000° at 201 nm. These data appear to be in reasonably good accord with recent calculations. Measurements of the absorption, linear dichroism and circular dichroism of polyproline I and II are also reported and are resolved into their component bands. Polyproline I is in good accord with exciton theory, whereas polyproline II remains unsatisfactory." @default.
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- W2042218564 date "1973-03-01" @default.
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- W2042218564 title "Ultraviolet circular dichroism of polyproline and oriented collagen" @default.
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