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- W2042244411 abstract "Layered Li(Ni1/3Co1/3Mn1/3)O2 was prepared by mixed hydroxide method and characterised by means of X-ray diffraction, X-ray photoelectron spectroscopy (XPS), cyclic voltammetry and charge–discharge cycling. The hexagonal lattice parameters obtained for the compound are: a=2.864 and c=14.233 Å. XPS studies show that the predominant oxidation states of Ni, Co and Mn in the compound are 2+, 3+ and 4+, respectively with small content of Ni3+ and Mn3+ ions. Initial discharge capacity of 160 mAh/g was obtained in the range 2.5–4.4 V and at a specific current of 30 mA/g of which 143 mAh/g was retained at the end of 40 charge–discharge cycles. At lower current (10 mA/g) and in the voltage window 2.5–4.7 V, discharge capacity of 215 mAh/g is obtainable. From the voltage profile and cyclic voltammetry, the redox processes occurring at ∼3.8 and ∼4.6 V are assigned to the Ni2+/4+ and Co3+/4+ couples, respectively." @default.
- W2042244411 created "2016-06-24" @default.
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- W2042244411 date "2002-11-01" @default.
- W2042244411 modified "2023-10-10" @default.
- W2042244411 title "Performance of layered Li(Ni1/3Co1/3Mn1/3)O2 as cathode for Li-ion batteries" @default.
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- W2042244411 doi "https://doi.org/10.1016/s0013-4686(02)00593-5" @default.
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