Matches in SemOpenAlex for { <https://semopenalex.org/work/W2042246080> ?p ?o ?g. }
- W2042246080 endingPage "109" @default.
- W2042246080 startingPage "98" @default.
- W2042246080 abstract "Abstract Raman study of cation and anion solvation in dimethyl sulfoxide, propylene carbonate and dimethyl carbonate solutions of six lithium salts has been performed in the concentration range from 0.05 to 0.25 molar fraction of a salt. The dependences of the amount of the solvent particles involved in dimerization, hydrogen bonding, and solvation have been determined, and the mean solvation numbers have been found. It is concluded that in all solutions studied, notwithstanding the differences in the physical properties of the solvent and in the structure of the anion, both the lithium cation and the anion solvation equilibria are quantitatively similar. In all cases, solvation numbers of cations are close to two and do not vary with the growth of concentration. In particular, in molten LiX·4S solvates, LiS 4 + entities expected from the phase diagrams do not exist. It has been found that for the solvent molecules in dimers and in solvation spheres, non-coincidences between vibrational frequencies of isotropic and anisotropic lines, Δ ν NCE = ν aniso − ν iso are of opposite signs signifying that the mutual orientation of molecules is different. In all systems studied, solvation numbers of anions decrease if the salt content is growing and are close to four in concentrated solutions. These striking similarities in the structure and concentration of solvated entities clearly signify that solvation phenomena have no decisive importance in determining the properties of salt systems." @default.
- W2042246080 created "2016-06-24" @default.
- W2042246080 creator A5018042633 @default.
- W2042246080 creator A5025459574 @default.
- W2042246080 creator A5077618039 @default.
- W2042246080 creator A5082812787 @default.
- W2042246080 date "2015-05-01" @default.
- W2042246080 modified "2023-10-18" @default.
- W2042246080 title "Raman study of solvation in solutions of lithium salts in dimethyl sulfoxide, propylene carbonate and dimethyl carbonate" @default.
- W2042246080 cites W117921956 @default.
- W2042246080 cites W1968924344 @default.
- W2042246080 cites W1973867177 @default.
- W2042246080 cites W1977284238 @default.
- W2042246080 cites W1981054057 @default.
- W2042246080 cites W1988638118 @default.
- W2042246080 cites W1990592251 @default.
- W2042246080 cites W1996792602 @default.
- W2042246080 cites W1997667317 @default.
- W2042246080 cites W1998775511 @default.
- W2042246080 cites W2010322837 @default.
- W2042246080 cites W2012104102 @default.
- W2042246080 cites W2015407010 @default.
- W2042246080 cites W2016974478 @default.
- W2042246080 cites W2017014438 @default.
- W2042246080 cites W2017978228 @default.
- W2042246080 cites W2018408948 @default.
- W2042246080 cites W2019014489 @default.
- W2042246080 cites W2024849145 @default.
- W2042246080 cites W2026529198 @default.
- W2042246080 cites W2027791297 @default.
- W2042246080 cites W2028106844 @default.
- W2042246080 cites W2028818325 @default.
- W2042246080 cites W2030638412 @default.
- W2042246080 cites W2031508523 @default.
- W2042246080 cites W2032853380 @default.
- W2042246080 cites W2035537551 @default.
- W2042246080 cites W2037120204 @default.
- W2042246080 cites W2042239496 @default.
- W2042246080 cites W2046081051 @default.
- W2042246080 cites W2046360548 @default.
- W2042246080 cites W2046621436 @default.
- W2042246080 cites W2052613390 @default.
- W2042246080 cites W2053170029 @default.
- W2042246080 cites W2053590220 @default.
- W2042246080 cites W2057948693 @default.
- W2042246080 cites W2059013645 @default.
- W2042246080 cites W2061808006 @default.
- W2042246080 cites W2065432479 @default.
- W2042246080 cites W2067725797 @default.
- W2042246080 cites W2069712426 @default.
- W2042246080 cites W2069765442 @default.
- W2042246080 cites W2084790269 @default.
- W2042246080 cites W2088411752 @default.
- W2042246080 cites W2088630388 @default.
- W2042246080 cites W2094957320 @default.
- W2042246080 cites W2095030164 @default.
- W2042246080 cites W2134749099 @default.
- W2042246080 cites W2161256109 @default.
- W2042246080 cites W2168713964 @default.
- W2042246080 cites W2169211003 @default.
- W2042246080 cites W2319310812 @default.
- W2042246080 cites W2330785212 @default.
- W2042246080 cites W2331706041 @default.
- W2042246080 cites W4211250518 @default.
- W2042246080 cites W4235158758 @default.
- W2042246080 cites W4235665919 @default.
- W2042246080 cites W4255152670 @default.
- W2042246080 cites W436120 @default.
- W2042246080 doi "https://doi.org/10.1016/j.molliq.2014.05.019" @default.
- W2042246080 hasPublicationYear "2015" @default.
- W2042246080 type Work @default.
- W2042246080 sameAs 2042246080 @default.
- W2042246080 citedByCount "17" @default.
- W2042246080 countsByYear W20422460802015 @default.
- W2042246080 countsByYear W20422460802016 @default.
- W2042246080 countsByYear W20422460802017 @default.
- W2042246080 countsByYear W20422460802018 @default.
- W2042246080 countsByYear W20422460802019 @default.
- W2042246080 countsByYear W20422460802020 @default.
- W2042246080 countsByYear W20422460802021 @default.
- W2042246080 countsByYear W20422460802022 @default.
- W2042246080 countsByYear W20422460802023 @default.
- W2042246080 crossrefType "journal-article" @default.
- W2042246080 hasAuthorship W2042246080A5018042633 @default.
- W2042246080 hasAuthorship W2042246080A5025459574 @default.
- W2042246080 hasAuthorship W2042246080A5077618039 @default.
- W2042246080 hasAuthorship W2042246080A5082812787 @default.
- W2042246080 hasConcept C120665830 @default.
- W2042246080 hasConcept C121332964 @default.
- W2042246080 hasConcept C134018914 @default.
- W2042246080 hasConcept C145148216 @default.
- W2042246080 hasConcept C147789679 @default.
- W2042246080 hasConcept C148093993 @default.
- W2042246080 hasConcept C17525397 @default.
- W2042246080 hasConcept C178790620 @default.
- W2042246080 hasConcept C179104552 @default.
- W2042246080 hasConcept C185592680 @default.
- W2042246080 hasConcept C2182769 @default.