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• W2042252105 abstract "Organic-solvent-soluble amphiphilic polyanilne was prepared by ion complex formation of protonated polyaniline (PANI) and anionic surfactant dodecylbenzenesulfonic acid (DBSA). The amphiphilic PANI/DBSA ion complex shows stable monolayer behavior at the air−water interface and formation of LB films on solid substrates. The cyclic voltammograms for the monolayer PANI/DBSA LB films show two distinct redox process waves, that is, the quasi-reversible redox wave at around 0.05 V vs SCE as a lucoemeralidine/emeraldine couple and the symmetric surface wave behavior of PANI at 0.75 V vs SCE as an emeraldine/pernigraniline couple. The surface morphology of the monolayer PANI/DBSA LB film on a Si wafer shows that monolayer surface roughness is smooth at a molecular level with fiberlike bundle structures where the elongated main chains of polyanilines were assembled by π−π interaction of the polyanilines. Conductivity of PANI/DBSA LB films depends on the number of layers at less than four layers, and it becomes similar to the bulk conductivity, 0.5 S/cm, at more than four layers." @default.
• W2042252105 created "2016-06-24" @default.
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• W2042252105 date "2008-12-18" @default.
• W2042252105 modified "2023-10-17" @default.
• W2042252105 title "Conductive Polyaniline/Surfactant Ion Complex Langmuir−Blodgett Films" @default.
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• W2042252105 doi "https://doi.org/10.1021/la803061e" @default.
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