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- W2042304987 abstract "Some novel techniques for volume localized, chemical shift selective (13) C spectroscopy are described in this work. These techniques are based on rotating frame J cross polarization and are reported for both direct and indirect modes of (13) C detection. The performance of two selective mixing sequences, viz., pulsed rotating frame transfer sequences with windows (PRAWN) and PRAWN-π has been studied systematically with different liquid and gel phantoms. Two different front-end modules are used for volume localization, viz., point resolved spectroscopy (PRESS) and localized distortionless enhancement by polarization transfer (LODEPT). It is shown experimentally that both the selective J cross polarization sequences can operate efficiently with very low radiofrequency duty cycle; further, they have considerable tolerance to Hartmann-Hahn mismatch. A simple theoretical analysis is also presented to understand J cross-polarization dynamics at low RF field amplitudes. Finally, the performance of LODEPT-PRAWN-π is demonstrated for the selective detection of saturated fat in pigeon egg in indirect detection mode." @default.
- W2042304987 created "2016-06-24" @default.
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- W2042304987 date "2011-04-05" @default.
- W2042304987 modified "2023-09-24" @default.
- W2042304987 title "Volume localized shift selective 13 C spectroscopy using pulsed rotating frame transfer sequences with windows (PRAWN)" @default.
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- W2042304987 doi "https://doi.org/10.1002/mrm.22915" @default.
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