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- W2042319778 abstract "A variety of aromatic, aliphatic and conjugated aldehydes and alcohols were transformed to the corresponding carboxylic acids and ketones with a quantitative conversion in high yields with 70% t-BuOOH solution in water in the presence of catalytic amounts of ceric ammonium nitrate [Ce(NH4)2(NO3)6] (CAN) under room temperature conditions. The scope of our catalytic system is applicable for a wide range of aromatic, conjugated and aliphatic substrates. These aldehydes were converted to the corresponding carboxylic acids in good isolated yields in reasonable times. This method possesses a wide range of capabilities since it can be used with other functional groups which may not tolerate oxidative conditions, involves fairly simple method for work-up, exhibits chemoselectivity and proceeds under ambient conditions. The resulting products are obtained in good yields within reasonable time." @default.
- W2042319778 created "2016-06-24" @default.
- W2042319778 creator A5025336463 @default.
- W2042319778 creator A5042094606 @default.
- W2042319778 date "2011-11-01" @default.
- W2042319778 modified "2023-10-01" @default.
- W2042319778 title "Ceric Ammonium Nitrate Catalyzed Oxidation of Aldehydes and Alcohols" @default.
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- W2042319778 doi "https://doi.org/10.1002/cjoc.201180406" @default.
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