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- W2042322005 abstract "Ultraviolet photoelectron spectra of CH3O−, CH3CH2O−, (CH3)2CHO−, (CH3)3CO−, as well as CD3O− and CD3CD2O− are presented, providing improved electron affinities and new information on vibronic coupling in the corresponding neutral radicals. Jahn-Teller vibronic transitions are assigned to e vibrational modes of X 2E CH3O. The excitation energy of the A 2A′ state of CH3CH2O with respect to the X 2A″ state is observed directly at 355±10 cm−1. Vibronic coupling between these low-lying electronic states perturbs the observed vibronic levels. Features of the (CH3)2CHO− photoelectron spectrum are assigned. The splitting between the X 2A′ and A 2A″ states of (CH3)2CHO is determined to be 1225±65 cm−1. Significant vibronic coupling is not observed in (CH3)2CHO. Vibrational assignments are made for the spectral features of (CH3)3CO and no Jahn-Teller effects are observed directly. Electron affinities (EAs) for the neutrals (RO) are (in eV); EA(CH3O)=1.572±0.004; EA(CD3O)=1.559±0.004; EA(CH3CH2O)=1.712±0.004; EA..." @default.
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- W2042322005 date "2000-01-15" @default.
- W2042322005 modified "2023-09-24" @default.
- W2042322005 title "Vibronic structure of alkoxy radicals via photoelectron spectroscopy" @default.
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- W2042322005 doi "https://doi.org/10.1063/1.480767" @default.
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