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- W2042332912 abstract "Kinetic study of the reaction of p-nitrophenyl diphenyl phosphate with 2-aminomethylphenols and the basic hydrolysis of ethyl p-nitrophenyl ethyl phosphonate have shown that in direct micelles the concentration factors is mainly responsible for the acceleration of nucleophilic substitution reaction while the micellar microenvironment negatively affects the reactivity and results in a diminution in the micellar rate effect. The considerable contribution to the micellar catalysis is made by the acid-base equilibrium shift of reagents. On the contrary, in reverse aggregates the micellar microenvironment favours the reaction and mostly underlies the mechanism of the catalysis, while the concentration factors plays a minor role." @default.
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- W2042332912 date "2001-10-01" @default.
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- W2042332912 title "The factors determining the micellar effects on nucleophilic substitution reactions" @default.
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- W2042332912 doi "https://doi.org/10.1016/s0167-7322(01)00244-6" @default.
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