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- W2042334105 abstract "Through utilizing the flexible bis(triazole) ligand 1,3-bis(1,2,4-triazol-1-y1)propane (btp), the new Keggin POM-templated compound, [Cd2(H2O)2(btp)4(SiMo12O40)]·2H2O (1), was synthesized under hydrothermal conditions. It was characterized by single-crystal X-ray diffraction, elemental analysis, IR spectroscopy, thermogravimetric analysis, photoluminescence spectroscopy, and cyclic voltammetry. In compound 1, the [SiMo12O40]4– polyanions serving as template induce the Cd–bis(triazole) coordination polymer to construct a ladder-like chain. In the 1D chain, two btp ligands act as “middle rails”. The template polyanions insert into the grids of the 1D chain. Furthermore, these chains can construct a 3D supramolecular structure through hydrogen bondings." @default.
- W2042334105 created "2016-06-24" @default.
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- W2042334105 date "2011-02-03" @default.
- W2042334105 modified "2023-09-27" @default.
- W2042334105 title "Assembly of a New Cadmium(II)-bis(Triazole) Coordination Polymer Templated by Keggin Polyoxometalate" @default.
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- W2042334105 doi "https://doi.org/10.1002/zaac.201000369" @default.
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