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- W2042345326 abstract "Abstract Two novel heptanuclear trigonal prismatic LnNi6 clusters, [SmNi6(Gly)6(Ac)(μ3-OH)3(μ2-H2O)2(im)6] · (ClO4)5 · (H2O)5 (1) and [GdNi6(Gly)6Cl3(OH)3(py)6] · Cl · (ClO4)2 · (H2O)5 (2), were synthesized through self-assembly, and were characterized by X-ray structure analyses. Complex 1 crystallizes in the monoclinic Cc space group (a = 17.9722(3) A, b = 16.3906(2) A, c = 25.3463(3) A, β = 99.832(1)° and Z = 4). Complex 2 attributes to the monoclinic P2(1)/c space group (a = 15.5408(2) A, b = 20.0516(4) A, c = 23.8204(4) A, β = 100.096(1)° and Z = 4). 1 has six terminal imidazole ligands, while 2 has six terminal pyridine ligands. The two complexes both have a [LnNi6(Gly)6(μ3-OH)3]6+ core. The magnetic measurements reveal that 1 exhibits an overall antiferromagnetic interaction, while 2 exhibits a ferromagnetic interaction." @default.
- W2042345326 created "2016-06-24" @default.
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- W2042345326 date "2006-01-01" @default.
- W2042345326 modified "2023-09-24" @default.
- W2042345326 title "Syntheses and characterization of two novel heptanuclear trigonal prismatic LnNi6 clusters with different terminal ligands" @default.
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- W2042345326 doi "https://doi.org/10.1016/j.poly.2005.04.030" @default.
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