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- W2042369828 abstract "The vapor-phase aldol condensation of methyl acetate (MeOAC) with formaldehyde (HCHO) to form methyl acrylate was investigated over solid base catalysts. A variety of solid base catalysts were prepared by loading Cs 2 O over SiO 2 or Al 2 O 3 as the support materials. The properties of the solid base catalysts were characterized by XRD, BET and CO 2 -TPD. The results of the vapor-phase aldol condensation indicated that SiO 2 and Al 2 O 3 modified with Cs 2 O showed high conversation of methyl acetate and high selectivity of methyl acrylate. 22.6% conversation of methyl acetate and 16.5% yield of acrylic acid and methyl acrylate were obtained over Cs-Al 2 O 3 . In addition, Cs-SiO 2 exhibited about 42% selectivity to methyl acetate. The high yield of acrylic acid and methyl acrylate is attributed to the high base property of catalysts." @default.
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- W2042369828 date "2012-12-01" @default.
- W2042369828 modified "2023-10-18" @default.
- W2042369828 title "Formation of Methyl Acrylate from Methyl Acetate and Formaldehyde Condensation over Solid Base Catalysts" @default.
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- W2042369828 doi "https://doi.org/10.4028/www.scientific.net/amr.629.376" @default.
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