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- W2042384458 abstract "Confacial bi-octahedral [Ru2(μ-Cl)3(AsMe2Ph)6]CF3SO3, (1), and [Ru2(μ-Br)3(AsMe3)6]CF3SO3, (2), are the first tertiary-arsine-capped systems within the wider class of redox-active [L3Ru(μ-X)3RuL3]+/2+ complexes (L = NR3, PR3 or AsR3; X = Cl or Br) to be structurally characterized. Compounds (1) and (2) have measured internuclear separations and mean bridgehead angles (RuII⋯RuII/Ru—X—Ru) of 3.275 (2)/83.5 and 3.413 (1) Å/81.8°, respectively." @default.
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- W2042384458 date "1996-04-15" @default.
- W2042384458 modified "2023-10-03" @default.
- W2042384458 title "Two `Ruthenium-Blue' Precursors: Tri-μ-chloro-hexakis(dimethylphenylarsine)diruthenium(II) Trifluoromethanesulfonate and Tri-μ-bromo-hexakis(trimethylarsine)diruthenium(II) Trifluoromethanesulfonate" @default.
- W2042384458 doi "https://doi.org/10.1107/s0108270195012534" @default.
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